改性TiO_2光催化降解三苯甲烷类污染物

以硫酸钛为原料采用水热法制备了掺Fe3＋TiO2晶体粉末,采用X射线衍射仪（XRD）对样品的结构进行了表征。在可见光条件下,用溴酚蓝、甲基绿、甲基蓝、孔雀石绿、甲基紫和碱性品红等6种典型三苯甲烷类化合物为目标降解物,研究了以自制的掺Fe3＋TiO2晶体粉末对它们的催化降解作用。实验结果表明,制备的掺Fe3＋TiO2晶体属于锐钛矿型。6种化合物的光催化降解反应遵循拟一级动力学规律,且可用Langmuir-Hinshelwood（L-H）动力学模型描述,其表观反应速度常数（k）的大小顺序为：溴酚蓝〈甲基绿〈甲基蓝〈孔雀石绿〈甲基紫〈碱性品红,大小变化次序与其半衰期t1/2成反比,并从分子结构上对它们的降解规律进行定性解释。     

Determination of antibiotics in sewage from hospitals, nursery and slaughter house, wastewater treatment plant and source water in Chongqing region of Three Gorge Reservoir in China

Sewage samples from 4 hospitals, 1 nursery, 1 slaughter house, 1 wastewater treatment plant and 5 source water samples of Chongqing region of Three Gorge Reservoir were analyzed for macrolide, lincosamide, trimethoprim, fluorouinolone, sulfonamide and tetracycline antibiotics by online solid-phase extraction and liquid chromatography-tandem mass spectrometry. Results showed that the concentration of ofloxacin (OFX) in hospital was the highest among all water environments ranged from 1.660 μg/L to 4.240 μg/L and norfloxacin (NOR, 0.136-1.620 μg/L), ciproflaxacin (CIP, ranged from 0.011 μg/L to 0.136 μg/L), trimethoprim (TMP, 0.061-0.174 μg/L) were commonly detected. Removal range of antibiotics in the wastewater treatment plant was 18-100% and the removal ratio of tylosin, oxytetracycline and tetracycline were 100%. Relatively higher removal efficiencies were observed for tylosin (TYL), oxytetracycline (OXY) and tetracycline (TET)(100%), while lower removal efficiencies were observed for Trimethoprim (TMP, 1%), Epi-iso-chlorotetracycline (EICIC, 18%) and Erythromycin-H₂O (ERY-H₂O, 24%). Antibiotics were removed more efficiently in primary treatment compared with those in secondary treatment.     

CCS scenarios optimization by spatial multi-criteria analysis: Application to multiple source sink matching in Hebei province

A method, based on spatial analysis of the different criteria to be taken into consideration for building scenarios of CO₂ capture and storage (CCS), has been developed and applied to real case studies in the Hebei province. Totally 88 point sources (42 from power sector, 9 from iron and steel, 18 from cement, 16 from ammonia, and 3 from oil refinery) are estimated and their total emission amounts to 231.7 MtCO₂/year with power, iron and steel, cement, ammonia and oil refinery sharing 59.13%, 25.03%, 11.44%, 3.5%, and 0.91%, respectively. Storage opportunities can be found in Hebei province, characterised by a strong tectonic subsidence during the Tertiary, with several kilometres of accumulated clastic sediments. Carbon storage potential for 25 hydrocarbon fields selected from the Huabei complex is estimated as 215 MtCO₂ with optimistic assumption that all recovered hydrocarbon could be replaced by an equivalent volume of CO₂ at reservoir conditions. Storage potential for aquifers in the Miocene Guantao formation is estimated as 747 MtCO₂ if closed aquifer assumed or 371 MtCO₂ if open aquifer and single highly permeable horizon assumed. Due to poor knowledge on deep hydrogeology and to pressure increase in aquifer, injecting very high rates requested by the major CO₂ sources (>10 MtCO₂/year) is the main challenge, therefore piezometry and discharge must be carefully controlled. A source sink matching model using ArcGIS software is designed to find the least-cost pathway and to estimate transport route and cost accounting for the additional costs of pipeline construction due to landform and land use. Source sink matching results show that only 15–25% of the emissions estimated for the 88 sources can be sequestrated into the hydrocarbon fields and the aquifers if assuming sinks should be able to accommodate at least 15 years of the emissions of a given source.     

Effect of ambient-level gas-phase peroxides on foliar injury, growth, and net photosynthesis in Japanese radish (Raphanus sativus)

To investigate the effects of ambient-level gas-phase peroxides concurrent with O₃ on foliar injury, photosynthesis, and biomass in herbaceous plants, we exposed Japanese radish (Raphanus sativus) to clean air, 50 ppb O₃, 100 ppb O₃, and 2-3 ppb peroxides + 50 ppb O₃ in outdoor chambers. Compared with exposure to 100 ppb O₃, exposure to 2-3 ppb peroxides + 50 ppb O₃ induced greater damage in foliar injury, net photosynthetic rates and biomass; the pattern of foliar injury and the cause of net photosynthetic rate reduction also differed from those occurring with O₃ exposure alone. These results indicate for the first time that sub-ppb peroxides + 50 ppb O₃ can cause more severe damage to plants than 100 ppb O₃, and that not only O₃, but also peroxides, could be contributing to the herbaceous plant damage and forest decline observed in Japan's air-polluted urban and remote mountains areas.     

Molecular detection and comparison of Acanthamoeba genotypes in different functions of watersheds in Taiwan

The protistan genus Acanthamoeba is a free-living amoeba existing in various environments. Within this protistan genus, there are some species recognized as potential human pathogens, which may cause granulomatous amoebic encephalitis, Acanthamoeba keratitis and chronic granulomatous lesions of the skin. In this study, 211 water samples were collected from two watersheds in southern Taiwan. We detected Acanthamoeba based on the PCR amplification with a genus-specific primer pair and investigation of Acanthamoeba in Puzih River and Kaoping River in southern Taiwan. Acanthamoeba species were detected in 34 (16.1%) samples. The presence or absence of Acanthamoeba within the water samples showed significant difference with the levels of water temperature and total coliforms. The most frequently identified Acanthamoeba genotype was T4 (n = 19), followed by T5 (n = 8), and then T15 (n = 3). Genotype T6, T7/T8, T11 and T12 were all detected once. Genotype T4, T5, T6, T11 and T15 of Acanthamoeba are responsible for Acanthamoeba keratitis and should be considered a potential health threat associated with human activities in environmental surface water watersheds.     

清洁发展机制在石油行业的潜力分析

系统分析了石油行业清洁发展机制项目的潜力,并提出了建议。在统计与石油行业相关的清洁发展机制方法学及其注册项目和温室气体减排量的基础上,给出了各方法学与石油行业的相关性。从勘探与生产、天然气与管道、炼油与化工三大领域,分析了石油行业潜在的清洁发展机制项目领域。最后,提出了对石油行业开展清洁发展机制相关工作的建议。     

活性污泥体系中聚糖菌的富集与鉴定

活性污泥体系中，聚糖菌(GAOs)在厌氧环境下与聚磷菌(PAOs)形成对底物的竞争关系，对聚糖菌的研究对于优化生物除磷工艺有重要意义。以葡萄糖为惟一碳源，在磷限制条件下，利用特殊运行方式对活性污泥进行驯化培养出了稳定的聚糖菌颗粒污泥，厌氧阶段磷释放量与有机物吸收量浓度(mg/L)比从7.4%下降为0.25%。从培养好的活性污泥反应器中分离获得2株聚糖菌，经菌落PCR和16S rRNA序列分析确定了所得聚糖菌菌株G1和菌株G2分别是枯草芽孢杆菌(Bacillus subtilis)和解鸟氨酸克雷伯氏菌(Klebsiella ornithinolytica)。     

An Interval-Parameter Waste-Load-Allocation Model for River Water Quality Management Under Uncertainty

A simulation-based interval quadratic waste load allocation (IQWLA) model was developed for supporting river water quality management. A multi-segment simulation model was developed to generate water-quality transformation matrices and vectors under steady-state river flow conditions. The established matrices and vectors were then used to establish the water-quality constraints that were included in a water quality management model. Uncertainties associated with water quality parameters, cost functions, and environmental guidelines were described as intervals. The cost functions of wastewater treatment units were expressed in quadratic forms. A water-quality planning problem in the Changsha section of Xiangjiang River in China was used as a study case to demonstrate applicability of the proposed method. The study results demonstrated that IQWLA model could effectively communicate the interval-format uncertainties into optimization process, and generate inexact solutions that contain a spectrum of potential wastewater treatment options. Decision alternatives can be generated by adjusting different combinations of the decision variables within their solution intervals. The results are valuable for supporting local decision makers in generating cost-effective water quality management strategies.     

Joint Impact of Scaling and Hysteresis on NAPL Flow Simulation

The hysteresis of capillary pressure versus saturation (P–S) relation is an important constitutive relation in multiphase flow, since the P–S relation is widely used to predict P–S relations in the simulation of the non-aqueous phase liquids (NAPLs). This work examined the performance of the scaling rule on predicting the P–S relationship and then studied the joint impact of the scaling and hysteresis on the multiphase NAPL flow simulation. Various experimental P–S values of distinct fluid pairs were compared with the scaled P–S curves using the scaling rule. The comparison indicated that the prediction of P–S is more accurate when the water–air P–S curve is used to scale other P–S curves. The joint impact of the scaling and hysteresis on the NAPLs flow simulation was then investigated by numerical simulation studies. The NAPL simulator was used to simulate the outcome of several scenarios based on a system with water–NAPL–air in a hypothetical sand tank. For both gasoline and trichloroethylene, the difference of the injected NAPL volume between no hysteretic and hysteretic simulations over a given time period was the smallest when the water–air P–S curve was used to scale other P–S curves. Simulation results of this study are valuable references for predicting the distribution of NAPLs.     

Gender differences in relation to wayfinding strategies, navigational support design, and wayfinding task difficulty

This study investigated user wayfinding navigational performance in terms of two navigational support designs (guide sign and you-are-here map, i.e., YAH), wayfinding strategies (egocentric/route and allocentric/survey), task difficulty (terrestrial/2D or weightless/3D), and gender differences. Eighty participants (40 males and 40 females) were recruited for the wayfinding experiment. The experimental results and statistical analysis indicated that, in the weightless VR scene, navigation time for the terrestrial/2D task type was significantly shorter than for the weightless/3D task type. The guide sign support was significantly more effective than YAH map support. Moreover, the interactions between support style and gender difference indicated that males exhibit better wayfinding performance than females, but that appropriate support can improve navigational performance and eliminate gender differences. In addition, the Way-Finding Strategy Scale result showed that the females were more likely to adopt the egocentric strategy while males were more likely to adopt the allocentric strategy, and that their scores were negatively correlated with navigational performance. Our results can be used to evaluate the interface designs of navigational support systems taking into consideration gender differences with respect to 3D VR games, including VR diving or flying navigational systems.